1-Benzoyl-4-thiobiuret

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1-Benzoyl-4-thio­biuret

IN THE TITLE COMPOUND (SYSTEMATIC NAME {[(phenyl-formamido)-carbon-yl]amino}-methane-thio-amide), C9H9N3O2S, both benzoyl and terminal thio-urea fragments adopt transoid conformations with respect to the central carbonyl O atom. The benzoyl and thio-biuret groups are almost coplanar, making a dihedral angle of 4.40 (8)°. The mol-ecular structure is stabilized by two intra-molecular N-H⋯O hydrog...

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1-Benzoyl-4-(4-methyl­phen­yl)phthal­azine

In the title mol-ecule, C(22)H(16)N(2)O, the tolyl and benzoyl rings make dihedral angles 50.2 (5) and 56.4 (5)°, respectively, with the phthalazine ring system while the dihedral angle between the tolyl and benzoyl rings is 0.70 (4)°. The crystal structure is stabilized by inter-molecular C-H⋯O and C-H⋯N hydrogen bonds, as well as weak C-H⋯π inter-actions.

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3-Benzoyl-1-[4-(methyl­sulfan­yl)phen­yl]thio­urea

The title compound, C15H14N2OS2, adopts a helix conformation. An intra-molecular N-H⋯O hydrogen bond leads to a six-membered pseudo-ring [r.m.s. deviation = 0.0212 Å, maximum deviation = 0.033 (1) Å for the N atom bearing the benzoyl group] in the central unit. The benzene and (methyl-sulfan-yl)benzene ring [r.m.s = 0.0028 Å and largest deviation of 0.067 (3) Å for the methyl-sulfanyl C atom] m...

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1-Benzoyl-3-(4-n-butyl­phen­yl)thio­urea

The dihedral angle between the benzoyl and phenyl groups in the title compound, C(18)H(20)N(2)OS, is 30.57 (4)°. The crystal packing is characterized by N-H⋯O hydrogen bonds. In the crysta, pairs of N-H⋯S hydrogen bonds link the molecules into inversion dimers.

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1-Benzoyl-4-(2-nitro­phen­yl)semicarbazide

The title compound, C(14)H(12)N(4)O(4), was prepared by the reaction of 2-nitro-phenyl isocyanate with benzoyl-hydrazine. The dihedral angle between the rings is 71.49 (6)) Å. The mol-ecular conformation is stabilized by an intra-molecular N-H⋯O hydrogen bond, generating an S(6) ring. The crystal packing shows N-H⋯O hydrogen bonds.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2013

ISSN: 1600-5368

DOI: 10.1107/s1600536813019983